Szukaj
Wyświetlanie pozycji 1-3 z 3
Ion Complexation Explains Orders of Magnitude Changes in the Equilibrium Constant of Biochemical Reactions in Buffers Crowded by Nonionic Compounds
(ASC Publications, 2022-01-13)
The equilibrium constant (K) of biochemical complex formation in aqueous buffers with high concentration (>20 wt %) of nonionic compounds can vary by orders of magnitude in comparison with the K in a pure buffer. The precise ...
Effective screening of Coulomb repulsions in water accelerates reactions of like-charged compounds by orders of magnitude
(Springer Nature, 2022-10-28)
The reaction kinetics between like-charged compounds in water is extremely slow due to Coulomb repulsions. Here, we demonstrate that by screening these interactions and, in consequence, increasing the local concentration ...
Thermodynamics of stationary states of the ideal gas in a heat flow
(AIP Publishing, 2022-11-01)
There is a long-standing question as to whether and to what extent it is possible to describe nonequilibrium systems in stationary states in terms of global thermodynamic functions. The positive answers have been obtained ...