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A quest for ideal electric field-driven MX@C70 endohedral fullerene memristors: which MX fits the best?
(Royal Society of Chemistry, 2023)Endohedral fullerenes with a dipolar molecule enclosed in the fullerene cage have great potential in molecular electronics, such as diodes, switches, or molecular memristors. Here, we study a series of model systems based ... -
Realization of nitroaromatic chromophores with intense two-photon brightness
(Royal Society of Chemistry, 2023)Strong fluorescence is a general feature of dipyrrolonaphthyridinediones bearing two nitrophenyl substituents. Methyl groups simultaneously being weakly electron-donating and inducing steric hindrance appear to be a key ... -
Recent advances in the application of nanoparticles in the selective reduction of carbon–carbon double bonds
(Elsevier, 2022)Herein, we present recent advances in the application of metal nanoparticles in the selective hydrogenation of C–C double bonds. The review focuses on reduction methods of alkenes, arenes, and aromatic heterocycles, which ... -
Recognition-Induced Enhanced Emission of Core-Fluorescent ESIPT-type Macrocycles
(Wiley, 2022)Core-fluorescent cavitandsbased on 2-(2′-resorcinol)benzimidazole fluorophores (RBIs)merged with the resorcin[4]arene skeleton were designed and synthesized. The cavitands, due to the presence of intramolecular ... -
Reductive Elimination from Sterically Encumbered Ni−Polypyridine Complexes
(American Chemical Society, 2022)Herein we disclose the synthesis of sterically encumbered dialkylnickel(II) complexes bearing 2,9-dimethyl-1,10-phenanthroline ligands. A comparison with their unsubstituted analogues by both X-ray crystallography and ... -
Relationship between Structure and Antibacterial Activity of α-Aminophosphonate Derivatives Obtained via Lipase-Catalyzed Kabachnik−Fields Reaction
(MDPI, 2022)We reported a new method dealing with the synthesis of novel pharmacologically relevant α-aminophosphonate derivatives via a lipase-catalyzed Kabachnik−Fields reaction with yields of up to 93%. The advantages of this ... -
Reply to: On the existence of collective interactions reinforcing the metal-ligand bond in organometallic compounds
(Nature Research, 2023)replying to J. Poater et al. Nature Communications https://doi.org/10.1038/s41467-023-39498-y (2023) -
Room-Temperature-Stable Magnesium Electride via Ni(II) Reduction
(American Chemical Society, 2022)Herein, we report the synthesis of highly reduced bipyridyl magnesium complexes and the first example of a stable organic magnesium electride supported by quantum mechanical computations and X-ray diffraction. These complexes ... -
Ruthenium Olefin Metathesis Catalysts Bearing a Macrocyclic N-Heterocyclic Carbene Ligand: Improved Stability and Activity
(Wiley, 2022)Formation of sterically hindered C−C double bonds via catalytic olefin metathesis is considered a very challenging task for Ru catalysts. This limitation led to the development of specialised catalysts bearing sterically ... -
Saddle-shaped aza-nanographene with multiple odd-membered rings
(Royal Society of Chemistry, 2023)A saddle-shaped aza-nanographene containing a central 1,4-dihydropyrrolo[3,2-b]pyrrole (DHPP) has been prepared via a rationally designed four-step synthetic pathway encompassing intramolecular direct arylation, the Scholl ... -
Selective Approaches to α- and β-Arylated Vinyl Ethers
(Wiley, 2022)We developed simple and efficient protocols for palladium-catalyzed regioselective a- and b-arylations of structurally diverse vinyl ethers. Both catalytic methods proceed under relatively mild reactions conditions ... -
Selective transformations of friedelanes isolated from cork smoker wash solids
(Elsevier, 2024)Friedelin (1) and 3-acetoxyfriedel-3-en-2-one (4), commonly known as friedelane triterpenoids, have been isolated from cork smoker wash solids (also known as black wax) on a multi-gram scale. These compounds are valuable ... -
Simultaneous Enantiodivergent Synthesis of Diverse Lactones and Lactams via Sequential One-Pot Enzymatic Kinetic Resolution–Ring-Closing Metathesis Reactions
(MDPI, 2022)One of the goals of diversity-oriented synthesis is to achieve the structural diversity of obtained compounds. As most biologically active compounds are chiral, it is important to develop enantioselective methods of their ... -
Singlet Fission in a New Series of Systematically Designed Through-space Coupled Tetracene Oligomers
(Wiley, 2024)Singlet fission (SF) holds great promise for current photovoltaic technologies, where tetracenes, with their relatively high triplet energies, play a major role for application in silicon-based solar cells. However, the ... -
Site-Selective, Photocatalytic Vinylogous Amidation of Enones
(American Chemical Society, 2022)Despite the broad interest in organic compounds possessing a γ-aminocarbonyl motif, limited strategies for their synthesis have been reported. Herein, we describe a mild and efficient method for the site-selective amidation ... -
Spatially resolved chiroptical study of thin films ofbenzo[1,2-b:4,5-b’]dithiophene-based oligothiophenes bysynchrotron radiation electronic circular dichroism imaging(SR-ECDi) technique
(Wiley, 2022)The study of the chiroptical properties of thin-film samples of two chiral benzo[1,2-b:4,5-b’]dithiophene-based oligothiophenes with optoelectronic properties was car-ried out at Diamond B23 beamline using the synchrotron ... -
Spectroscopic and Crystallographic Characterization of Two Hydrochloride Cathinones: 1-(4-fluoro-3-methylphenyl)-2-(pyrrolidin-1-yl)pentan-1-one (4-F-3-Me-α-PVP) and N-ethyl-2-amino-1-phenylheptan-1-one (N-ethylheptedrone)
(MDPI, 2023)In this paper, two cathinone derivatives, 4F-3Me-alfa-PVP and N-ethylheptedrone, seized on the illegal drug market in Poland, were described and characterized by various instrumental analytical methods. The compounds were ... -
Spinristor: A Spin-Filtering Memristor
(Wiley, 2023)In this paper, an in silico proof of concept of a spinristor is proposed and provided; a new electronic component that combines a spin-filter and a memristor in a single molecule, useful for in-memory processing. It builds ... -
The Study on Timolol and Its Potential Phototoxicity Using Chemical, In Silico and In Vitro Methods
(MDPI, 2024)Timolol (TIM) is a non-selective ß-adrenergic receptor antagonist used orally for the treatment of hypertension and heart attacks, and topically for treating glaucoma; lately, it has also been used in some specific ... -
Synthesis and Antimicrobial Activity of the Pathogenic E. coli Strains of p-Quinols: Additive Effects of Copper-Catalyzed Addition of Aryl Boronic Acid to Benzoquinones
(MDPI, 2023)A mild and efficient protocol for the synthesis of p-quinols under aqueous conditions was developed. The pivotal role of additives in the copper-catalyzed addition of aryl boronic and heteroaryl boronic acids to benzoquinones ...