dc.contributor.author | Potrząsaj, Aleksandra | |
dc.contributor.author | Ociepa, Michał | |
dc.contributor.author | Chaładaj, Wojciech | |
dc.contributor.author | Gryko, Dorota | |
dc.date.accessioned | 2022-06-23T09:45:59Z | |
dc.date.available | 2022-06-23T09:45:59Z | |
dc.date.issued | 2022-03-25 | |
dc.identifier.citation | Org. Lett. 2022, 24, 2469−2473. https://doi.org/10.1021/acs.orglett.2c00355 | en |
dc.identifier.issn | 1523-7060 | |
dc.identifier.issn | 1523-7052 | |
dc.identifier.other | 10.1021/acs.orglett.2c00355 | |
dc.identifier.uri | https://depot.ceon.pl/handle/123456789/21367 | |
dc.description.abstract | Oxetanes are valuable building blocks due to their well-explored propensity to undergo ring-opening reactions with nucleophiles. However, their application as precursors of radical
species is still elusive. Herein, we present a bioinspired cobalt catalysis-based strategy to access unprecedented modes of radical
reactivity via oxetane ring-opening. This powerful approach gives access to nucleophilic radicals that engage in reactions with SOMOphiles and low-valent transition metals. Importantly, the regioselectivity of these processes complements known methodologies. | en |
dc.description.sponsorship | National Science Foundation (MAESTRO UMO-2020/38/A/ST4/00185)
Foundation for Polish Sciences (FNP TEAM POIR.04.04.00−00−4232/17−00; START 64.2020)
Wrocław Centre for Networking and Supercomputing (http://wcss.pl), grant No. 518. | |
dc.language.iso | en | |
dc.publisher | American Chemical Society | en |
dc.rights | Creative Commons Uznanie autorstwa 4.0 | * |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/legalcode | * |
dc.subject | alkyls | en |
dc.subject | chemical reactions | en |
dc.subject | ethers | en |
dc.subject | organic compounds | en |
dc.subject | ring opening reactions | en |
dc.title | Bioinspired Cobalt-Catalysis Enables Generation of Nucleophilic Radicals from Oxetanes | en |
dc.type | article | en |
dc.contributor.organization | Institute of Organic Chemistry, Polish Academy of Sciences | en |